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Comptes Rendus Chimie
Volume 18, n° 7
pages 785-789 (juillet 2015)
Doi : 10.1016/j.crci.2015.04.007
Received : 18 February 2015 ;  accepted : 22 April 2015
Dinuclear palladium(I) sandwich complexes of furan and toluene
 

Koji Yamamoto b, c, Yuki Ishikawa b, c, Seita Kimura b, d, Kohei Takase d, Tetsuro Murahashi a, b,
a Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152-8552, Japan 
b Research Center of Integrative Molecular Systems (CIMoS), Institute for Molecular Science, National Institutes of Natural Science, Myodaiji, Okazaki, Aichi, 444-8787, Japan 
c Department of Structural Molecular Science, the Graduate University of Advanced Sciences, Myodaiji, Okazaki, Aichi, 444-8787, Japan 
d Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan 

Corresponding author at: Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152-8552, Japan.
Abstract

The reaction of a dinuclear palladium complex [Pd2 (CH3 CN)6 ][X]2 (X=BF4 , PF6 ) with excess furan afforded the sandwich-type bis-furan dinuclear palladium(I) complex [Pd2 (μ-furan)2 (CH3 CN)2 ][X]2 . The substitutionally labile bridging furan ligands in the dipalladium sandwich complex can be readily replaced with toluene to give the bis-toluene dipalladium(I) sandwich complex [Pd2 (μ-toluene)2 (CH3 CN)2 ][X]2 .

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Keywords : Palladium, Sandwich complexes, Heterocycles, Arenes




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