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Comptes Rendus Chimie
Volume 18, n° 5
pages 581-585 (mai 2015)
Doi : 10.1016/j.crci.2014.09.002
Received : 12 July 2014 ;  accepted : 1 September 2014
Silica/A153–SO3 H: An efficient catalyst for the Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide
 

Wanzhen Xing, Qingguo Ma, Xinhua Peng
 School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China 

Corresponding author.
Abstract

Silica/A153–SO3 H was prepared and characterized by FT–IR, TG and SEM. It proved to be an efficient and recyclable heterogeneous catalyst in the Baeyer–Villiger (BV) oxidation of cyclic ketones with H2 O2 as an oxidant. Catalysts with different silica particle sizes were also made comparisons in terms of catalytic effect.

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Keywords : Silica, Baeyer–Villiger oxidation, Heterogeneous catalyst, Recyclable catalyst




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